Furan → HCID 22457278, compound

HRID 2184636Notes

Reaction equation

HRID 2184636 reaction equation
[O:1]1[CH:5]=[CH:4][CH:3]=[CH:2]1.Cl[C:7]1[C:12](=O)[C:11](Cl)=[C:10](Cl)[C:9](=O)[C:8]=1Cl>C1(C)C=CC=CC=1>[C:7]1([C:2]2[O:1][C:5]([C:7]3[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=3)=[C:4]3[C:3]=2[CH:5]=[C:4]([C:7]2[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=2)[C:3]([C:7]2[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=2)=[CH:2]3)[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1

Participants

4

Reactant 2

HCID 8029FuranHCID 8371Chloranil

Product 1

HCID 22457278HCID 22457278, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

Next, the dihydro-compound of furan and tetrachloro-p-benzoquinone (chloranyl) in toluene were heated under reflux to effect dehydrogenation, yielding 1,3,5,6-tetraphenylisobenzofuran.

Workup

  1. temperatureunder reflux

Sources & evidence

ORD record
ord-420f6f82c96341558336fcbdf8944c4e
Source dataset
uspto-grants-2002_06
Patent number
US06399223B1

Reaction notes

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