HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2185604Generated: October 25, 2026
Hexafluoropropylene → HCID 12654514, compound
https://huagongshe.com/reaction/2185604
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Hexafluoropropylene | HCID 8302 | — |
| Reactant | Pentanoyl fluoride, 2,2,3,3,4,4,5,5,5-nonafluoro- | HCID 67812 | — |
| Reactant | Potassium Fluoride | HCID 522689 | — |
| Reactant | HCID 178506425 | HCID 178506425 | — |
| Solvent | Diglyme | HCID 8150 | — |
| Product | HCID 12654514 | HCID 12654514 | 440.2% |
Reaction Steps
A mixture consisting of 775 g of perfluoropentanoyl fluoride, 800 g of anhydrous diglyme, 13.1 g of potassium fluoride, 17.8 g of anhydrous potassium bifluoride and 775 g of hexafluoropropylene was heated in a 3-liter stainless steel pressure vessel under autogeneous pressure at 50° C. for 16 hours. The product was fractionally distilled to give 413 g of 1,1,1,2,4,4,5,5,6,6,7,7,7-tridecafluoro-2-trifluoromethyl-heptan-3-one, having a boiling point of 97° C. and a 99.0% purity as determined by gas chromatography and mass spectroscopy.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US06403149B1 |
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| Source dataset | uspto-grants-2002_06 |
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| ORD ID | ord-5ea6f8fe7af64b238303f92b11956b52 |
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| Source note | uspto-grants-2002_06 |
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