Sodium Dithionite → HCID 22452563, compound

HRID 2185918Notes

Reaction equation

HRID 2185918 reaction equation
[C:1]([C:4]1[O:5][C:6]2[C:15]([C:16]([OH:18])=[O:17])=[CH:14][CH:13]=[CH:12][C:7]=2[C:8](=[O:11])[C:9]=1[CH3:10])(=[O:3])C.CC1C(=O)C2C=CC=C(C=CC)C=2OC=1[C:34](=O)[NH:35]C.S(S([O-])=O)([O-])=O.[Na+].[Na+]>>[C:16]([C:15]1[C:6]2[O:5][C:4]([C:1]([NH:35][CH3:34])=[O:3])=[C:9]([CH3:10])[C:8](=[O:11])[C:7]=2[CH:12]=[CH:13][CH:14]=1)([OH:18])=[O:17]

Participants

4

Reactant 3

HCID 24489Sodium DithioniteHCID 22452562HCID 22452562, compoundHCID 69971553HCID 69971553, compound

Product 1

HCID 22452563HCID 22452563, compoundYield 60%

Procedure

The title compound was prepared following the method described for Compound 2C but using Compound 5A instead of Compound 2B. The reaction mixture was poured into an 1% aqueous solution of sodium dithionite and filtered after overnight resting to give Compound 5B (60%).

Workup

  1. customThe title compound was prepared
  2. filtrationfiltered after overnight

Sources & evidence

ORD record
ord-eff30b3b958d42a7ad8ecfdd3ba48fdf
Source dataset
uspto-grants-2002_06
Patent number
US06403594B1

Reaction notes

Loading…