HCID 9812838, compound → HCID 21348849, compound

HRID 2186534Notes

Reaction equation

HRID 2186534 reaction equation
[C:1]([O:4][C:5]([CH2:10][CH3:11])([CH2:8][CH3:9])[CH2:6][CH3:7])(=[O:3])[CH3:2].[CH:12]12[CH2:18][CH:15]([CH:16]=[CH:17]1)[CH2:14][CH:13]2[CH2:19][CH2:20][CH2:21][C:22](=[O:24])[CH3:23]>>[OH:24][C:22]([CH3:23])([CH2:21][CH2:20][CH2:19][CH:13]1[CH2:14][CH:15]2[CH2:18][CH:12]1[CH:17]=[CH:16]2)[CH2:2][C:1]([O:4][C:5]([CH2:8][CH3:9])([CH2:6][CH3:7])[CH2:10][CH3:11])=[O:3]

Participants

3

Reactant 2

HCID 9812838HCID 9812838, compoundHCID 22456925HCID 22456925, compound

Product 1

HCID 21348849HCID 21348849, compoundYield 91%

Procedure

The procedure of Synthesis Example 1 was repeated except that 3-ethyl-3-pentyl acetate was used instead of 1-ethylcyclopentyl acetate, and 5-(5-norbornen-2-yl)-2-pentanone was used instead of 5-norbornene-2-carbaldehyde. There was obtained 3-ethyl-3-pentyl 3-hydroxy-3-methyl-6-(5-norbornen-2-yl)hexanoate. Yield 91%.

Workup

  1. customThe procedure of Synthesis Example 1

Sources & evidence

ORD record
ord-71eea70912674302bf120bcbe0d44985
Source dataset
uspto-grants-2002_06
Patent number
US06403822B2

Reaction notes

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