HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tributylstannane → Acetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tributylstannane | HCID 5948 | — |
| Reactant | Heptane | HCID 8900 | — |
| Reactant | Iodoethanol | HCID 12225 | — |
| Reactant | 1-Hydroxy-4-benzoyloxy-2,2,6,6-tetramethylpiperidine | HCID 688178 | — |
| Solvent | Chlorobenzene | HCID 7964 | — |
| Product | Acetate | HCID 175 | — |
| Product | HCID 22507676 | HCID 22507676 | — |
Reaction Steps
Tributyltin hydride is added dropwise to a solution of 2-iodoethanol and 4-benzoyloxy-1-oxyl-2,2,6,6-tetramethylpiperidine in chlorobenzene. The crude reaction mixtuire is passed through silica gel with heptane and then heptanelethyl acetate to afford the title compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06403681B2 |
| Source dataset | uspto-grants-2002_06 |
| ORD ID | ord-5209b91c10544e4b92cdb7c91f70c58b |
| Source note | uspto-grants-2002_06 |