Lithium propan-2-olate → HCID 178459136, compound

HRID 2187308Notes

Reaction equation

HRID 2187308 reaction equation
[CH3:1][CH:2]([CH3:4])[O-:3].[Li+:5].[CH3:6][CH:7]([CH3:9])[O-:8].[CH3:10][Ga+:11][CH3:12]>C(OCC)C>[CH3:1][CH:2]([CH3:4])[O-:3].[CH3:10][Ga+:11][CH3:12].[Li+:5].[CH3:6][CH:7]([CH3:9])[O-:8]

Participants

4

Reactant 2

HCID 23673350Lithium propan-2-olateHCID 178459281HCID 178459281, compound

Product 1

HCID 178459136HCID 178459136, compoundYield 85%

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

1.32 g (20.0 mmol) of lithium isopropoxide was added to 3.18 g (20.0 mmol) of dimethylgallium isopropoxide dissolved in diethyl ether and stirred for a day. The solvent was removed under a reduced pressure to obtain 3.82 g (17.0 mmol; 85% yield) of the title compound in the form of a white solid.

Workup

  1. customThe solvent was removed under a reduced pressure

Sources & evidence

ORD record
ord-3de15a7ce0b349f2b086efd3d5fc2e28
Source dataset
uspto-grants-2002_06
Patent number
US06409830B1

Reaction notes

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