HRID2189436

反应详情

EQUATION

反应方程式

REACTANTS

反应物

反应SMILES：CN(C)CCCNS(=O)(=O)c1ccccc1[N+](=O)[O-]

HCID4125491

未命名化合物

反应SMILES：CC(C)(NS(=O)(=O)c1ccccc1[N+](=O)[O-])C(N)=O

HCID23078874

未命名化合物

反应SMILES：CC(=O)OC[C@H]1O[C@@H](Oc2n[nH]c(C(C)C)c2Cc2ccc(OCCCO)cc2C)[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@H]1OC(C)=O

HCID68938067

未命名化合物

PRODUCTS

产物

反应SMILES：Cc1cc(OCCCNCCCN(C)C)ccc1Cc1c(O[C@@H]2O[C@H](CO)[C@H](O)[C@H](O)[C@H]2O)n[nH]c1C(C)C

HCID68947831

未命名化合物

PROCEDURE

实验过程

The title compound was prepared in a similar manner to that described in Example 51 using 3-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyloxy)-4-{[4-(3-hydroxypropoxy)-2-methylphenyl]methyl}-5-isopropyl-1H-pyrazole and N,N-dimethyl-N′-(2-nitrobenzenesulfonyl)-1,3-diaminopropane instead of 3-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy)-4-{[4-(3-hydroxypropoxy)-2-methylphenyl]methyl}-5-isopropyl-1H-pyrazole and 2-methyl-2-(2-nitrobenzenesulfonylamino)propionamide, respectively.

来源与证据

来源类型: Open Reaction Database
ORD记录: ord-1fa9233e59a04098b67a7697fbb66446
来源数据集: uspto-grants-2012_12
DOI: 10.6084/m9.figshare.5104873.v1
专利号: US08324176B2
来源说明: uspto-grants-2012_12

反应SMILES

C([O:4][C@@H:5]1[C@@H:10]([O:11]C(=O)C)[C@@H:9]([O:15]C(=O)C)[C@@H:8]([CH2:19][O:20]C(=O)C)[O:7][C@H:6]1[O:24][C:25]1[C:29]([CH2:30][C:31]2[CH:36]=[CH:35][C:34]([O:37][CH2:38][CH2:39][CH2:40]O)=[CH:33][C:32]=2[CH3:42])=[C:28]([CH:43]([CH3:45])[CH3:44])[NH:27][N:26]=1)(=O)C.[CH3:46][N:47]([CH3:64])[CH2:48][CH2:49][CH2:50][NH:51]S(C1C=CC=CC=1[N+]([O-])=O)(=O)=O.CC(NS(C1C=CC=CC=1[N+]([O-])=O)(=O)=O)(C)C(N)=O>>[C@@H:6]1([O:24][C:25]2[C:29]([CH2:30][C:31]3[CH:36]=[CH:35][C:34]([O:37][CH2:38][CH2:39][CH2:40][NH:51][CH2:50][CH2:49][CH2:48][N:47]([CH3:64])[CH3:46])=[CH:33][C:32]=3[CH3:42])=[C:28]([CH:43]([CH3:45])[CH3:44])[NH:27][N:26]=2)[O:7][C@H:8]([CH2:19][OH:20])[C@H:9]([OH:15])[C@H:10]([OH:11])[C@H:5]1[OH:4]