HCID 86649338, compound → HCID 86649337, compound

HRID 218970Notes

Reaction equation

HRID 218970 reaction equation
[C:1]([P:5]([C:10]1[CH:15]=[CH:14][C:13]([CH3:16])=[C:12]([P:17]([C:24]2[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=2)[C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)[C:11]=1[CH3:30])[C:6]([CH3:9])([CH3:8])[CH3:7])([CH3:4])([CH3:3])[CH3:2].P.P>COCCO>[C:1]([P:5]([C:10]1[CH:15]=[CH:14][C:13]([CH3:16])=[C:12]([P:17]([C:24]2[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=2)[C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)[C:11]=1[CH3:30])[C:6]([CH3:7])([CH3:9])[CH3:8])([CH3:2])([CH3:3])[CH3:4]

Participants

3

Reactant 1

HCID 86649338HCID 86649338, compound

Product 1

HCID 86649337HCID 86649337, compoundYield 87%

Reagents, catalysts & solvents 1

HCID 80192-MethoxyethanolSolvent

Procedure

Diphosphine (di-t-butylphosphino)(diphenylphosphino)-m-xylene (0.1 g, 0.23 mmol), [Ir2Cl2(cyclooctene)4] (0.1 g, 0.12 mmol) in 2-methoxyethanol (8 cm3) were heated under reflux for 2 days. The solvent was then removed under reduced pressure to give a brown solid (0.13 g, 0.2 mmol, 86%) of structure:

Workup

  1. temperatureunder reflux for 2 days
  2. customThe solvent was then removed under reduced pressure

Sources & evidence

ORD record
ord-e4646af5d7f242328c559120180e3025
Source dataset
uspto-grants-2012_06
Patent number
US08198476B2

Reaction notes

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