HuagongsheHuagongshe Chemistry Print Report · For research reference only
Formic Acid → Dodecane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Formic Acid | HCID 284 | — |
| Reactant | Sulfuric Acid | HCID 1118 | — |
| Reactant | Tetrahydrofuran | HCID 8028 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | Dodecane | HCID 8182 | 83% |
Reaction Steps
HMF, THF, formic acid (4 equiv.), H2SO4 (3 mol %, relative to HMF) and Pd/C (8 mol %) were stirred at 100° C. to yield DMF in 83% yield by gas chromatography relative to a dodecane standard.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08324409B2 |
| Source dataset | uspto-grants-2012_12 |
| ORD ID | ord-eacaa311b8f04194afb90f43ac17569c |
| Source note | uspto-grants-2012_12 |