Cyclohexane, (bromomethyl)- → HCID 67523654, compound

HRID 2190927Notes

Reaction equation

HRID 2190927 reaction equation
[OH:1][C:2]1[CH:3]=[CH:4][C:5]2[O:10][C:9]([CH3:12])([CH3:11])[O:8][C:7](=[O:13])[C:6]=2[CH:14]=1.Br[CH2:16][CH:17]1[CH2:22][CH2:21][CH2:20][CH2:19][CH2:18]1>>[CH:17]1([CH2:16][O:1][C:2]2[CH:3]=[CH:4][C:5]3[O:10][C:9]([CH3:11])([CH3:12])[O:8][C:7](=[O:13])[C:6]=3[CH:14]=2)[CH2:22][CH2:21][CH2:20][CH2:19][CH2:18]1

Participants

3

Reactant 2

HCID 137636Cyclohexane, (bromomethyl)-HCID 67421272HCID 67421272, compound

Product 1

HCID 67523654HCID 67523654, compound

Procedure

The title compound was prepared from 6-hydroxy-2,2-dimethyl-benzo[1,3]dioxin-4-one (example 38.a) and (bromomethyl)cyclohexane under conditions analogous to experimental example 38-b, to give the desired product as a white solid. MS: (+) m/z 291.05 (M+1)

Sources & evidence

ORD record
ord-69bc9a177921456b877a19251d3e7b8f
Source dataset
uspto-grants-2012_12
Patent number
US08324405B2

Reaction notes

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