O-Phenylenediamine → 5,7,12,14-Tetrahydroquinoxalino[2,3-b]phenazine

HRID 2194970Notes

Reaction equation

HRID 2194970 reaction equation
[NH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[NH2:8].O[C:10]1[CH:15]=[C:14](O)[C:13](O)=[CH:12][C:11]=1O>>[CH:4]1[C:3]2[NH:8][C:11]3[C:10](=[CH:15][C:14]4[NH:1][C:2]5[C:3]([NH:8][C:13]=4[CH:12]=3)=[CH:4][CH:5]=[CH:6][CH:7]=5)[NH:1][C:2]=2[CH:7]=[CH:6][CH:5]=1

Participants

3

Reactant 2

HCID 7243O-PhenylenediamineHCID 694641,2,4,5-Benzenetetrol

Product 1

HCID 145343855,7,12,14-Tetrahydroquinoxalino[2,3-b]phenazine

Procedure

Alternatively, the at least one 1,2-diaminobenzene compound and the 1,2,4,5-tetrahydroxybenzene compound can be combined to form a mixture, and the mixture is then heated in an inert environment to form the 5,7,12,14-tetrahydro-5,7,12,14-tetraazapentacene compound. The mixture can be heated at a temperature above 300° C., and the mixture can be heated for a time period of from about 30 seconds to about 10 minutes.

Workup

  1. customto form a mixture
  2. temperaturethe mixture is then heated in an inert environment

Sources & evidence

ORD record
ord-4752427ac756472592cb0a0eee89f4d4
Source dataset
uspto-grants-2012_12
Patent number
US08334384B2

Reaction notes

Loading…