1-Bromo-4-tert-butylbenzene → Tris(4-tert-butylphenyl)sulfanium bromide

HRID 219508Notes

Reaction equation

HRID 219508 reaction equation
[C:1]([C:5]1[CH:10]=[CH:9][C:8]([S:11]([C:13]2[CH:18]=[CH:17][C:16]([C:19]([CH3:22])([CH3:21])[CH3:20])=[CH:15][CH:14]=2)=O)=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2].[C:23]([C:27]1[CH:32]=[CH:31][C:30]([Br:33])=[CH:29][CH:28]=1)([CH3:26])([CH3:25])[CH3:24]>>[Br-:33].[C:1]([C:5]1[CH:10]=[CH:9][C:8]([S+:11]([C:30]2[CH:31]=[CH:32][C:27]([C:23]([CH3:26])([CH3:25])[CH3:24])=[CH:28][CH:29]=2)[C:13]2[CH:18]=[CH:17][C:16]([C:19]([CH3:22])([CH3:21])[CH3:20])=[CH:15][CH:14]=2)=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2]

Participants

3

Reactant 2

HCID 775951-Bromo-4-tert-butylbenzeneHCID 184321184,4'-Sulfinylbis(tert-butylbenzene)

Product 1

HCID 23149384Tris(4-tert-butylphenyl)sulfanium bromide

Procedure

The intended compound was obtained by a similar manner to that in Synthesis Example 1 except that bis(4-tert-butylphenyl)sulfoxide instead of diphenyl sulfoxide and 4-tert-butylbromobenzene instead of chlorobenzene were used, and the amount of water in the extraction was increased.

Workup

  1. customThe intended compound was obtained by a similar manner to that
  2. extractionthe amount of water in the extraction
  3. temperaturewas increased

Sources & evidence

ORD record
ord-8b33147d851c48608e7e7a3f0279346a
Source dataset
uspto-grants-2012_06
Patent number
US08202677B2

Reaction notes

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