HuagongsheHuagongshe Chemistry Print Report · For research reference only
Vinyl Acetate → 2-Vinyl-2-azabicyclo[2.2.1]hept-5-en-3-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Vinyl Acetate | HCID 7904 | — |
| Reactant | 2-Azabicyclo(2.2.1)hept-5-en-3-one | HCID 548678 | — |
| Catalyst | HCID 178479786 | HCID 178479786 | — |
| Product | 2-Vinyl-2-azabicyclo[2.2.1]hept-5-en-3-one | HCID 60007647 | — |
Reaction Steps
A solution of 2-azabicyclo[2.2.1]hept-5-en-3-one (0.5 g, 4.6 mmole) in vinyl acetate (3 ml, 33 mmole) with sodium tetrachloropalladate (15 mg, 0.05 mmole) was refluxed for 5 days. The product, Compound 6, was isolated by evaporation of the volatiles. Analysis by Gas Liquid Chromatography-Mass Spectrometry (GLC-MS) was consistent with the predicted molecular weight.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08202833B2 |
| Source dataset | uspto-grants-2012_06 |
| ORD ID | ord-3865ab6554404ec9b59a3a1abbb6b7da |
| Source note | uspto-grants-2012_06 |