HCID 86658918, compound → Sapienic acid

HRID 2195625Notes

Reaction equation

HRID 2195625 reaction equation
O[CH:2]([CH3:19])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH:10]=[CH:11][CH2:12][CH2:13][CH2:14][CH2:15][C:16]([OH:18])=[O:17].OC(CC)CCCCCCC=CCCCCC(O)=O.OC(CCC)CCCCCC=CCCCCC(O)=O>>[C:16]([OH:18])(=[O:17])[CH2:15][CH2:14][CH2:13][CH2:12]/[CH:11]=[CH:10]\[CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH3:19]

Participants

4

Reactant 3

HCID 86658918HCID 86658918, compoundHCID 86658919HCID 86658919, compoundHCID 86658920HCID 86658920, compound

Product 1

HCID 5312419Sapienic acid

Procedure

The total amount of 15-hydroxy-6-hexadecenoic acid, 14-hydroxy-6-hexadecenoic acid and 13-hydroxy-6-hexadecenoic acid obtained by the reaction was 460 mg, and the ratio was such that 15-hydroxy-6-hexadecenoic acid: 51.3%, 14-hydroxy-6-hexadecenoic acid: 35.5%, and 13-hydroxy-6-hexadecenoic acid: 13.2%, respectively.

Sources & evidence

ORD record
ord-e801bda01ce545429f4e08e2f125e1e0
Source dataset
uspto-grants-2012_12
Patent number
US08338361B2

Reaction notes

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