Triacetoxyperiodinane → HCID 59843139, compound

Participants

Reaction Steps

To a stirred solution of 153 (650 mg, 1.550 mmol) in DCM (7.75 ml) under N2 was added Dess-Martin periodinane (0.50 ml, 1.627 mmol) and the mixture was stirred at room temperature for 3 h. The reaction mixture was taken to dryness and the residue was purified by chromatography (Biotage 15 to 65% EtOAc in hexane) to afford 154 (565 mg, 1.35 mmol, 88%). LRMS (ESI): (calc.) 417.1 (found) 440.2 (MNa)+.

Provenance & Evidence