Stannous Chloride → HCID 13500181, compound

HRID 2197718Notes

Reaction equation

HRID 2197718 reaction equation
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([S:9][C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)=[C:5]([N+:16]([O-])=O)[CH:4]=1.Cl[Sn]Cl>>[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([S:9][C:10]2[CH:11]=[CH:12][CH:13]=[CH:14][CH:15]=2)=[C:5]([NH2:16])[CH:4]=1

Participants

3

Reactant 2

HCID 24479Stannous ChlorideHCID 684578344-Methoxy-2-nitro-1-phenylsulfanyl-benzene

Product 1

HCID 13500181HCID 13500181, compoundYield 96.6%

Procedure

The product from Example 9a (2.70 g, 10.2 mmol) was reacted with SnCl2 (9.40 g, 50.0 mmol) for 22 h following the procedure from Example 1f giving the title compound as a white solid (2.28 g, 96%).

Sources & evidence

ORD record
ord-890724e379c74111821085e04da54cb4
Source dataset
uspto-grants-2012_12
Patent number
US08338605B2

Reaction notes

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