3,4-Dimethoxybenzene-1-thiol → HCID 68457787, compound

HRID 2197773Notes

Reaction equation

HRID 2197773 reaction equation
[CH3:1][C:2]1[CH:7]=[CH:6][C:5](OS(C(F)(F)F)(=O)=O)=[C:4]([N+:16]([O-])=O)[CH:3]=1.[CH3:19][O:20][C:21]1[CH:22]=[C:23]([SH:29])[CH:24]=[CH:25][C:26]=1[O:27][CH3:28]>>[CH3:19][O:20][C:21]1[CH:22]=[C:23]([S:29][C:5]2[CH:6]=[CH:7][C:2]([CH3:1])=[CH:3][C:4]=2[NH2:16])[CH:24]=[CH:25][C:26]=1[O:27][CH3:28]

Participants

3

Reactant 2

HCID 1365393,4-Dimethoxybenzene-1-thiolHCID 713468894-Methyl-2-nitrophenyl trifluoromethanesulfonate

Product 1

HCID 68457787HCID 68457787, compoundYield 71.3%

Procedure

The product from Example 4a (11.25 g, 39.5 mmol) was reacted with 3,4-dimethoxy-benzenethiol (6.71 g, 39.5 mmol) for 18 h following the procedure from Example 4b giving the product as a solid (7.75 g, 64%).

Sources & evidence

ORD record
ord-39dd6e0c8def42d28b90f8056c5da904
Source dataset
uspto-grants-2012_12
Patent number
US08338605B2

Reaction notes

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