Stannous Chloride → 3-(2-Amino-4-methyl-phenylsulfanyl)-phenol

HRID 2197775Notes

Reaction equation

HRID 2197775 reaction equation
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][C:9]2[CH:10]=[C:11]([OH:15])[CH:12]=[CH:13][CH:14]=2)=[C:4]([N+:16]([O-])=O)[CH:3]=1.Cl[Sn]Cl>>[NH2:16][C:4]1[CH:3]=[C:2]([CH3:1])[CH:7]=[CH:6][C:5]=1[S:8][C:9]1[CH:10]=[C:11]([OH:15])[CH:12]=[CH:13][CH:14]=1

Participants

3

Reactant 2

HCID 24479Stannous ChlorideHCID 602047953-(4-Methyl-2-nitro-phenylsulfanyl)-phenol

Product 1

HCID 574699063-(2-Amino-4-methyl-phenylsulfanyl)-phenol

Procedure

The product from Example 52a was reduced with SnCl2 following the procedure from Example 1f giving the title compound.

Sources & evidence

ORD record
ord-31bfdfe5706d40c58bdc63c5073d6074
Source dataset
uspto-grants-2012_12
Patent number
US08338605B2

Reaction notes

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