Stannous Chloride → 2-(2,5-Dimethyl-furan-3-ylsulfanyl)-5-methyl-phenylamine

HRID 2197811Notes

Reaction equation

[CH3:1][C:2]1[O:3][C:4]([CH3:18])=[CH:5][C:6]=1[S:7][C:8]1[CH:13]=[CH:12][C:11]([CH3:14])=[CH:10][C:9]=1[N+:15]([O-])=O.Cl[Sn]Cl>>[CH3:1][C:2]1[O:3][C:4]([CH3:18])=[CH:5][C:6]=1[S:7][C:8]1[CH:13]=[CH:12][C:11]([CH3:14])=[CH:10][C:9]=1[NH2:15]

Participants

Reactant 2

HCID 24479Stannous Chloride

HCID 684583602,5-Dimethyl-3-(4-methyl-2-nitro-phenylsulfanyl)-furan

Product 1

HCID 684612932-(2,5-Dimethyl-furan-3-ylsulfanyl)-5-methyl-phenylamine

Procedure

The product from Example 91a was reduced with SnCl2 following the procedure from Example 1f to give the title compound.

Sources & evidence

ORD record: ord-592201bc90f1445083cd7bde5091e0dd
Source dataset: uspto-grants-2012_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08338605B2

Reaction notes

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