Stannous Chloride → HCID 68459017, compound

HRID 2197894Notes

Reaction equation

HRID 2197894 reaction equation
[Cl:1][C:2]1[CH:18]=[CH:17][C:5]([O:6][C:7]2[CH:16]=[CH:15][C:10]([C:11]([NH:13][CH3:14])=[O:12])=[CH:9][CH:8]=2)=[C:4]([N+:19]([O-])=O)[CH:3]=1.Cl[Sn]Cl>>[NH2:19][C:4]1[CH:3]=[C:2]([Cl:1])[CH:18]=[CH:17][C:5]=1[O:6][C:7]1[CH:16]=[CH:15][C:10]([C:11]([NH:13][CH3:14])=[O:12])=[CH:9][CH:8]=1

Participants

3

Reactant 2

HCID 24479Stannous ChlorideHCID 68460694HCID 68460694, compound

Product 1

HCID 68459017HCID 68459017, compoundYield 55.6%

Procedure

The product from Example 162a (200 mg, 0.65 mmol) was reacted with SnCl2 as described in Example 1f to give the title compound (100 mg, 55%).

Sources & evidence

ORD record
ord-f8962b255aac48ae80ceaae22a191a1d
Source dataset
uspto-grants-2012_12
Patent number
US08338605B2

Reaction notes

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