Stannous Chloride → HCID 68461940, compound

HRID 2197919Notes

Reaction equation

HRID 2197919 reaction equation
[Cl:1][C:2]1[CH:24]=[CH:23][C:5]([O:6][C:7]2[CH:8]=[C:9]([CH:20]=[CH:21][CH:22]=2)[C:10]([NH:12][C:13]2[CH:18]=[CH:17][CH:16]=[C:15]([OH:19])[CH:14]=2)=[O:11])=[C:4]([N+:25]([O-])=O)[CH:3]=1.Cl[Sn]Cl>>[NH2:25][C:4]1[CH:3]=[C:2]([Cl:1])[CH:24]=[CH:23][C:5]=1[O:6][C:7]1[CH:8]=[C:9]([CH:20]=[CH:21][CH:22]=1)[C:10]([NH:12][C:13]1[CH:18]=[CH:17][CH:16]=[C:15]([OH:19])[CH:14]=1)=[O:11]

Participants

3

Reactant 2

HCID 24479Stannous ChlorideHCID 68458768HCID 68458768, compound

Product 1

HCID 68461940HCID 68461940, compoundYield 84%

Procedure

The product from Example 174b (1.0 g, 2.6 mmol) was reacted with SnCl2 as described in Example 1f to give the title compound (0.71 g, 84%).

Sources & evidence

ORD record
ord-373ca6143a9e4609b6bdfdfee21558ec
Source dataset
uspto-grants-2012_12
Patent number
US08338605B2

Reaction notes

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