Stannous Chloride → HCID 26189322, compound

HRID 2197925Notes

Reaction equation

HRID 2197925 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([O:8][C:9]2[CH:14]=[CH:13][C:12]([CH:15]([CH3:17])[CH3:16])=[CH:11][CH:10]=2)=[C:4]([N+:18]([O-])=O)[CH:3]=1.Cl[Sn]Cl>>[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([O:8][C:9]2[CH:14]=[CH:13][C:12]([CH:15]([CH3:17])[CH3:16])=[CH:11][CH:10]=2)=[C:4]([NH2:18])[CH:3]=1

Participants

3

Reactant 2

HCID 24479Stannous ChlorideHCID 68456703HCID 68456703, compound

Product 1

HCID 26189322HCID 26189322, compoundYield 84.4%

Procedure

The product from Example 179a (13.7 g, 46.8 mmol) was reacted with SnCl2 as described in Example 1f to give the title compound (10.3 g, 84.4%).

Sources & evidence

ORD record
ord-8cfff13e72514d7e84e79b8f5dd2d660
Source dataset
uspto-grants-2012_12
Patent number
US08338605B2

Reaction notes

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