HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dicyclohexylamine → HCID 68459222, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dicyclohexylamine | HCID 7582 | — |
| Reactant | Undecane | HCID 14257 | — |
| Reactant | Phenylboronic Acid | HCID 66827 | — |
| Reactant | 4-Bromo-3-nitrotoluene | HCID 79224 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 68459222 | HCID 68459222 | 42% |
Reaction Steps
1-Bromo-4-methyl-2-nitro-benzene (0.107 g, 0.49 mmol) was reacted as described in Example 215a substituting 3-acetamidophenylboronic acid (0.086 g, 0.49 mmol) for phenylboronic acid, dicyclohexylamine (4 mole %) for 2,8,9-triisobutyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3.]undecane and substituting dioxane for toluene to give the title biphenyl (0.0552 g, 42%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08338605B2 |
| Source dataset | uspto-grants-2012_12 |
| ORD ID | ord-4991174665c447e2878a72f597656ea1 |
| Source note | uspto-grants-2012_12 |