HuagongsheHuagongshe Chemistry Print Report · For research reference only
Trichloromethanesulfenyl chloride → 5-Cyano-1-(2,6-dimethylphenyl)-6-methyl-3-trichloromethanesulfenyluracil
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Trichloromethanesulfenyl chloride | HCID 11666 | — |
| Reactant | Sodium | HCID 5360545 | — |
| Reactant | 5-Carbamoyl-1-(2,6-dimethylphenyl)uracil | HCID 13014498 | — |
| Reactant | 5-Cyano-1-(2,6-dimethylphenyl)-6-methyluracil | HCID 13014501 | — |
| Reactant | HCID 20519703 | HCID 20519703 | — |
| Product | 5-Cyano-1-(2,6-dimethylphenyl)-6-methyl-3-trichloromethanesulfenyluracil | HCID 20519665 | — |
| Product | 5-Carbamoyl-1-(2,6-dimethylphenyl)-3-trichloromethanesulfenyluracil | HCID 20519693 | — |
| Product | 1-(2,6-Dimethylphenyl)-3-trichloromethanesulfenyluracil | HCID 20519726 | — |
Reaction Steps
Following the procedure of Example 1, the sodium salt of each of 5-cyano-1-(2,6-dimethylphenyl)-6-methyluracil, 5-carbamoyl-1-(2,6-dimethylphenyl)uracil and 1-(2,6-dimethylphenyl)uracil is reacted with trichloromethanesulfenyl chloride to yield 5-cyano-1-(2,6-dimethylphenyl)-6-methyl-3-trichloromethanesulfenyluracil, 5-carbamoyl-1-(2,6-dimethylphenyl)-3-trichloromethanesulfenyluracil and 1-(2,6-dimethylphenyl)-3-trichloromethanesulfenyluracil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04358591 |
| Source dataset | uspto-grants-1982_11 |
| ORD ID | ord-df0564bc89fd4d38b2640965754f3cdd |
| Source note | uspto-grants-1982_11 |