Water → HCID 54162902, compound

HRID 2198815Notes

Reaction equation

HRID 2198815 reaction equation
[CH2:1]([OH:4])[CH:2]=[CH2:3].N1C=CC=CC=1.[Cl:11][C:12]1[CH:32]=[C:31]([Br:33])[CH:30]=[CH:29][C:13]=1[O:14][C:15]1[CH:28]=[CH:27][C:18]([O:19][C:20](=[CH:24][CH2:25][CH3:26])[C:21](Cl)=O)=[CH:17][CH:16]=1.[OH2:34]>C1C=CC=CC=1>[Cl:11][C:12]1[CH:32]=[C:31]([Br:33])[CH:30]=[CH:29][C:13]=1[O:14][C:15]1[CH:16]=[CH:17][C:18]([O:19][CH:20]([CH3:21])[CH:24]=[CH:25][C:26]([O:4][CH2:1][CH:2]=[CH2:3])=[O:34])=[CH:27][CH:28]=1

Participants

6

Reactant 4

HCID 962WaterHCID 1049PyridineHCID 7858Allyl AlcoholHCID 86738635HCID 86738635, compound

Product 1

HCID 54162902HCID 54162902, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

In a mixture of 70 ml of benzene, 2.1 g (0.030 mole) of allyl alcohol and 2.6 g (0.033 mole) of pyridine, 12.5 g (0.03 mole) of [4-(2-chloro-4-bromophenoxy) phenoxy]2-pentenoic chloride obtained in the previous Preparation was added to react them at room temperature. Water was added to the reaction mixture and the benzene phase was washed with water and dehydrated over anhydrous sodium sulfate and benzene was distilled off to obtain 11.5 g of an orange viscous liquid having ND20 :1.5757 (yield 87.3%).

Workup

  1. customobtained in the previous Preparation
  2. additionwas added
  3. customto react them at room temperature
  4. washthe benzene phase was washed with water
  5. distillationwas distilled off

Sources & evidence

ORD record
ord-861a6f0b4b5f46b9b0a6eaa9ef6d8b1e
Source dataset
uspto-grants-1982_11
Patent number
US04360375

Reaction notes

Loading…