Water → HCID 20517774, compound

HRID 2198934Notes

Reaction equation

HRID 2198934 reaction equation
[CH3:1][C:2]1([CH3:11])[C:4]([C:5]2[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=2)=[N:3]1.[CH2:12]([N:15]([CH2:24][CH2:25][CH3:26])[C:16]1[CH:23]=[CH:22][C:19]([CH:20]=[O:21])=[CH:18][CH:17]=1)[CH2:13][CH3:14].O>C1C=CC=CC=1>[CH2:24]([N:15]([CH2:12][CH2:13][CH3:14])[C:16]1[CH:17]=[CH:18][C:19]([CH:20]2[O:21][C:2]([CH3:1])([CH3:11])[N:3]=[C:4]2[C:5]2[CH:6]=[CH:7][CH:8]=[CH:9][CH:10]=2)=[CH:22][CH:23]=1)[CH2:25][CH3:26]

Participants

5

Reactant 3

HCID 962WaterHCID 69171Benzaldehyde, 4-(dipropylamino)-HCID 3082152,2-Dimethyl-3-phenyl-2H-azirene

Product 1

HCID 20517774HCID 20517774, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

10 g of 2,2-dimethyl-3-phenyl-2H-azirine and 10 g of 4-dipropylaminobenzaldehyde were exposed to light in 2 liters of benzene under an atmosphere of argon for 40 minutes with a mercury high-pressure lamp of 2000 watt in a ring-mantle vessel through an interposed filter fluid. The filter fluid contained 35 g of cupric sulfate pentahydrate per liter of water and had a layer thickness of 1 cm. Not only the reaction solution but also the filter solution were cooled during the exposure to light in that they circulated with aid of pumps through a heat-exchanger positioned outside the photoreactor. During the exposure to light the temperature of the reaction solution amounted to 26° C. measured outside the photoreactor.

Workup

  1. temperatureNot only the reaction solution but also the filter solution were cooled during the exposure to light in that they
  2. customamounted to 26° C.

Sources & evidence

ORD record
ord-5731719a728e4802bf5a0b237391d223
Source dataset
uspto-grants-1982_11
Patent number
US04360530

Reaction notes

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