HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2198999Generated: November 3, 2026
Carbon Dioxide → Trimethylsilyl trichloroacetate
https://huagongshe.com/reaction/2198999
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Carbon Dioxide | HCID 280 | — |
| Reactant | Phenol | HCID 996 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | Trimethylsilyl trichloroacetate | HCID 117484 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | Trimethylsilyl trichloroacetate | HCID 117484 | — |
| Product | trimethyl(trichloromethyl)silane | HCID 3372381 | — |
Reaction Steps
Phenol (1.17 g, 0.0125 mole), trimethylsilyl trichloroacetate (3.53 g, 0.015 mole), potassium carbonate (0.035 g) and 18-crown-6 polyether (0.066 g) were placed in a 25-ml round-bottom flask fitted with a distillation head. A dry ice receiver and dry ice trap were attached. The mixture was heated to 150° C. Gas evolution proceeded rapidly and liquid chloroform and CCl3SiMe3 (formed by the base-induced decomposition of trimethylsilyl trichloroacetate) collected in the dry ice trap.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US04360686 |
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| Source dataset | uspto-grants-1982_11 |
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| ORD ID | ord-bcc5525e9a8f46a7b8814a656756e7d5 |
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| Source note | uspto-grants-1982_11 |
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