Trioctylphosphine → HCID 87238518, compound

HRID 2201338Notes

Reaction equation

[Se:1].[CH2:2]([P:10]([CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26])[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]>>[Se:1].[CH2:19]([P:10]([CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9])[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])[CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26]

Participants

Reactant 2

HCID 20851Trioctylphosphine

HCID 6326970Selenium

Product 1

HCID 87238518HCID 87238518, compound

Procedure

Separately, selenium (Se) powder is dissolved in trioctylphosphine (TOP), providing a 2 Molar (M) Se-TOP complex solution. About 2 mL of the 2M Se-TOP complex solution is quickly injected into the about 300° C. reaction mixture while being agitated and reacted for about 2 minutes.

Sources & evidence

ORD record: ord-82dc044c3e954bc6b1911303105e8aa6
Source dataset: uspto-grants-2016_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US09362189B2

Reaction notes

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