Water → Phenol

HRID 2201592Notes

Reaction equation

HRID 2201592 reaction equation
[CH:1]1([C:7]2[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=2)[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[OH2:13]>>[C:1]1(=[O:13])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[C:1]1([OH:13])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH3:7][CH:12]1[CH2:8][CH2:9][CH2:10][C:11]1=[O:13]

Participants

5

Reactant 2

HCID 962WaterHCID 13229Cyclohexylbenzene

Product 3

HCID 996PhenolHCID 7967CyclohexanoneHCID 142652-Methylcyclopentanone

Procedure

The neutralized cleavage reaction product mixture can then be separated by methods such as distillation. In one example, in a first distillation column after the cleavage reactor, a heavies fraction comprising the amine salt is obtained at the bottom of the column, a side fraction comprising cyclohexylbenzene is obtained in the middle section, and an upper fraction comprising cyclohexanone, phenol, methylcyclopentanone, and water is obtained.

Workup

  1. customThe neutralized cleavage reaction product mixture can then be separated by methods such as distillation
  2. customis obtained at the bottom of the column
  3. customis obtained in the middle section

Sources & evidence

ORD record
ord-e0d1ce55635c4dd191bcbd2f4901781f
Source dataset
uspto-grants-2016_06
Patent number
US09364819B2

Reaction notes

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