HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2204932Generated: October 31, 2026
Phenyl isocyanate → 2-[(Phenylcarbamoyl)oxy]ethyl prop-2-enoate
https://huagongshe.com/reaction/2204932
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Phenyl isocyanate | HCID 7672 | — |
| Reactant | 2-Hydroxyethyl acrylate | HCID 13165 | — |
| Reactant | 2,6-Di-tert-butyl-4-methylphenol | HCID 31404 | — |
| Reactant | N,N',N''-Tris(3-dimethylaminopropyl)hexahydro-S-triazine | HCID 85160 | — |
| Reactant | Isocyanate | HCID 105034 | — |
| Product | 2-[(Phenylcarbamoyl)oxy]ethyl prop-2-enoate | HCID 21463909 | — |
Reaction Steps
A 500 ml round-bottom flask was initially charged with 0.25 g of 2,6-di-tert-butyl-4-methylphenol, 0.12 g of Desmorapid Z and 126.4 g of phenyl isocyanate, and the mixture was heated to 60° C. Subsequently, 123.3 g of 2-hydroxyethyl acrylate were added dropwise and the mixture was kept at 60° C. until the isocyanate content had fallen below 0.1%. This was followed by cooling. The product was obtained as a crystalline solid (preparation described in DE 2329142). The product has a melting point of 66-68° C. (Bowman, Macromolecules, 2004, 37 (11), 4062-4069).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US09366957B2 |
|---|
| Source dataset | uspto-grants-2016_06 |
|---|
| ORD ID | ord-33d5930390e5453d9282cb80f1bacd39 |
|---|
| Source note | uspto-grants-2016_06 |
|---|
