Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Tin tetrachloride → (E)-1-methoxy-8-methyl-10-pentyl-3,4,5,6,9,10-hexahydroazecin-2(1H)-one
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Tin tetrachloride | HCID 24287 | — |
| 반응물 | Cyclohexanone, 2-(1-methylethenyl)- | HCID 11018939 | — |
| 반응물 | HCID 53992913 | HCID 53992913 | — |
| 용매 | 1,2-Dichloroethane | HCID 11 | — |
| 생성물 | (E)-1-methoxy-8-methyl-10-pentyl-3,4,5,6,9,10-hexahydroazecin-2(1H)-one | HCID 131735803 | 59% |
반응 단계
Following the general procedure as described in Example 17, 2-(prop-1-en-2-yl)cyclohexanone (0.88 g, 6.38 mmol), hexanal O-ethyl oxime (0.99 g, 7.65 mmol), and SnCl4 (1.66 g, 6.38 mmol) in 1,2-dichloroethane (65 ml) were reacted to give the title product as a colorless liquid (1.00 g, 59% yield). E isomer>98%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US09371262B2 |
| 출처 데이터셋 | uspto-grants-2016_06 |
| ORD ID | ord-4cf36810dec34a169919c08b278a0534 |
| 출처 메모 | uspto-grants-2016_06 |