HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tin tetrachloride → (E)-1-methoxy-9,11-dimethylazacycloundec-8-en-2-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tin tetrachloride | HCID 24287 | — |
| Reactant | Acetaldehyde, O-methyloxime | HCID 535486 | — |
| Reactant | 2-(Prop-1-en-2-yl)cycloheptanone | HCID 71426214 | — |
| Solvent | 1,2-Dichloroethane | HCID 11 | — |
| Product | (E)-1-methoxy-9,11-dimethylazacycloundec-8-en-2-one | HCID 131735805 | 90% |
Reaction Steps
Following the general procedure as described in Example 17, 2-(prop-1-en-2-yl)cycloheptanone (0.97 g, 6.38 mmol), acetaldehyde O-methyl oxime (0.56 g, 7.65 mmol), and SnCl4 (1.66 g, 6.38 mmol) in 1,2-dichloroethane (65 ml) were reacted to give the title product as a colorless liquid (1.29 g, 90% yield).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09371262B2 |
| Source dataset | uspto-grants-2016_06 |
| ORD ID | ord-c5123d77941e4b1bae63926ebdd05f9a |
| Source note | uspto-grants-2016_06 |