Hexane → HCID 53241517, compound

HRID 2205270Notes

Reaction equation

HRID 2205270 reaction equation
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].[OH-].[K+].[CH3:9][N:10]([CH3:16])[CH2:11][CH:12]([OH:15])[CH2:13]O.CS([O:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29]/[CH:30]=[CH:31]\[CH2:32]/[CH:33]=[CH:34]\[CH2:35][CH2:36][CH2:37][CH2:38][CH3:39])(=O)=O>O>[CH2:22]([O:21][CH:11]([N:10]([CH3:16])[CH3:9])[CH:12]([O:15][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:22][CH2:23]/[CH:24]=[CH:25]\[CH2:26]/[CH:27]=[CH:28]\[CH2:29][CH2:30][CH2:31][CH2:32][CH3:33])[CH3:13])[CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29]/[CH:30]=[CH:31]\[CH2:32]/[CH:33]=[CH:34]\[CH2:35][CH2:36][CH2:37][CH2:38][CH3:39]

Participants

6

Reactant 4

HCID 8058HexaneHCID 14797Potassium HydroxideHCID 790783-(Dimethylamino)-1,2-propanediolHCID 59753235Linoleyl methanesulfonate

Product 1

HCID 53241517HCID 53241517, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

In a nitrogen atmosphere, hexane (30 mL), potassium hydroxide (3.1 g, 54.4 mmol), and water (0.6 g: 3 parts by weight relative to 100 parts by weight of hexane) were added to a four-necked flask, and 3-(dimethylamino)-1,2-propanediol (0.72 g, 6.04 mmol: DAP) was dropped under agitation. Thereafter, linoleyl methane sulfonate (5.0 g, 14.5 mmol) was added, and agitation was performed at 40° C. for 19 hours. The reaction was terminated because remaining linoleyl methane sulfonate became 1.0% (degree of conversion: 64.0%, integrated value of isomer: 0.009).

Workup

  1. customThe reaction was terminated

Sources & evidence

ORD record
ord-12361ab6d9cb4a3ea36a216d19fc3fdd
Source dataset
uspto-grants-2016_06
Patent number
US09371271B2

Reaction notes

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