Stannane, tributyl(1-ethoxyethenyl)- → HCID 118557934, compound

HRID 2207203Notes

Reaction equation

HRID 2207203 reaction equation
Br[C:2]1[CH:3]=[N:4][CH:5]=[CH:6][C:7]=1[CH2:8][CH:9]1[CH2:17][C:16]2[C:11](=[CH:12][CH:13]=[C:14]([Cl:18])[CH:15]=2)[C:10]1=[O:19].[CH2:20]([O:22]C([Sn](CCCC)(CCCC)CCCC)=C)[CH3:21]>>[C:20]([C:2]1[CH:3]=[N:4][CH:5]=[CH:6][C:7]=1[CH2:8][CH:9]1[CH2:17][C:16]2[C:11](=[CH:12][CH:13]=[C:14]([Cl:18])[CH:15]=2)[C:10]1=[O:19])(=[O:22])[CH3:21]

Participants

3

Reactant 2

HCID 619414Stannane, tributyl(1-ethoxyethenyl)-HCID 118557864HCID 118557864, compound

Product 1

HCID 118557934HCID 118557934, compound

Procedure

The title compound 110 is prepared according to the procedure reported in Example 36.5 with compound 109 (317 mg, 0.94 mmol) and (1-ethoxyvinyl)tri(n-butyl)stannane (0.31 mL, 0.94 mmol) as reactants. White solid. (Yield 221 mg, 78%).

Sources & evidence

ORD record
ord-a072b7f7b76f4c3594a1c5e60918a375
Source dataset
uspto-grants-2016_06
Patent number
US09376387B2

Reaction notes

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