Stannane, tributyl(1-ethoxyethenyl)- → HCID 118557874, compound

HRID 2207204Notes

Reaction equation

HRID 2207204 reaction equation
Br[C:2]1[CH:3]=[N:4][CH:5]=[CH:6][C:7]=1[CH2:8][CH:9]1[CH2:17][C:16]2[C:11](=[CH:12][C:13]([CH3:19])=[C:14]([CH3:18])[CH:15]=2)[C:10]1=[O:20].[CH2:21]([O:23]C([Sn](CCCC)(CCCC)CCCC)=C)[CH3:22]>>[C:21]([C:2]1[CH:3]=[N:4][CH:5]=[CH:6][C:7]=1[CH2:8][CH:9]1[CH2:17][C:16]2[C:11](=[CH:12][C:13]([CH3:19])=[C:14]([CH3:18])[CH:15]=2)[C:10]1=[O:20])(=[O:23])[CH3:22]

Participants

3

Reactant 2

HCID 619414Stannane, tributyl(1-ethoxyethenyl)-HCID 118557926HCID 118557926, compound

Product 1

HCID 118557874HCID 118557874, compound

Procedure

The title compound 111 is prepared according to the procedure reported in Example 36.5 with compound 107 (235 mg, 0.71 mmol) and (1-ethoxyvinyl)tri(n-butyl)stannane (0.24 mL, 0.71 mmol) as reactants. White solid. (Yield 125.0 mg, 60%).

Sources & evidence

ORD record
ord-c4d1ed3c09cc4d019b6f7e90a7150860
Source dataset
uspto-grants-2016_06
Patent number
US09376387B2

Reaction notes

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