Stannane, tributyl(1-ethoxyethenyl)- → HCID 118557916, compound

HRID 2207205Notes

Reaction equation

HRID 2207205 reaction equation
Br[C:2]1[CH:3]=[N:4][CH:5]=[CH:6][C:7]=1[CH2:8][CH:9]1[CH2:17][C:16]2[C:11](=[CH:12][CH:13]=[C:14]([O:18][CH3:19])[CH:15]=2)[C:10]1=[O:20].[CH2:21]([O:23]C([Sn](CCCC)(CCCC)CCCC)=C)[CH3:22]>>[C:21]([C:2]1[CH:3]=[N:4][CH:5]=[CH:6][C:7]=1[CH2:8][CH:9]1[CH2:17][C:16]2[C:11](=[CH:12][CH:13]=[C:14]([O:18][CH3:19])[CH:15]=2)[C:10]1=[O:20])(=[O:23])[CH3:22]

Participants

3

Reactant 2

HCID 619414Stannane, tributyl(1-ethoxyethenyl)-HCID 118558045HCID 118558045, compound

Product 1

HCID 118557916HCID 118557916, compound

Procedure

The title compound 113 is prepared according to the procedure reported in Example 36.5 with compound 106 (235 mg, 0.71 mmol) and (1-ethoxyvinyl)tri(n-butyl)stannane (0.34 mL, 0.99 mmol) as reactants. White solid. (Yield 135 mg, 64%).

Sources & evidence

ORD record
ord-ce0b237b6e5744e0bfcc087ad9c17027
Source dataset
uspto-grants-2016_06
Patent number
US09376387B2

Reaction notes

Loading…