HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → HCID 86711729, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Sodium Carbonate | HCID 10340 | — |
| Reactant | 9,10-Dibromoanthracene | HCID 68226 | — |
| Reactant | HCID 58876089 | HCID 58876089 | — |
| Catalyst | HCID 178418397 | HCID 178418397 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 86711729 | HCID 86711729 | 68% |
Reaction Steps
Following the procedure as outlined above for synthesizing Compound 5, Compound (2.686 g, 7.274 mmol), 9,10-dibromoanthracene (7.333 g, 21.82 mmol), tetrakis(triphenylphosphine)palladium(0) (0.420 g, 0.364 mmol), Na2CO3 (9.539 g, 90.00 mmol), H2O (90 mL) and THF (150 mL) yielded Compound 8 (2.45 g, 68%) as a light yellow solid after flash chromatography (SiO2, 19:1 to 9:1 hexanes-dichloromethane).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09379336B2 |
| Source dataset | uspto-grants-2016_06 |
| ORD ID | ord-55c6c852a9664050a724d5b740992b71 |
| Source note | uspto-grants-2016_06 |