1-Chloro-1-chloromethyl-1-silacyclopentane → 1-Chloromethyl-1-(4-chlorophenyl)-1-silacyclopentane

Participants

Reaction Steps

In the same apparatus and procedures as Example 1 was reacted 83 ml of 4-chlorophenylmagnesiumbromide solution (1.0 M in diethylether) with 1-chloro-1-chloromethyl-1-silacyclopentane prepared from the above procedure i) for 5 hrs. In the same method as Example 1 was treated the reaction product to give 5.20 g of 1-chloromethyl-1-(4-chlorophenyl)-1-silacyclopentane (b.p. 108°-110° C./0.5 mmHg).

Provenance & Evidence