Silane, trichloro(1-chloroethyl)- → HCID 19382023, compound

HRID 2209829Notes

Reaction equation

HRID 2209829 reaction equation
[Cl:1][CH:2]([Si:4]([Cl:7])(Cl)[Cl:5])[CH3:3].[F:8][C:9]1[CH:14]=[CH:13][C:12]([Mg]Br)=[CH:11][CH:10]=1>>[Cl:1][CH:2]([Si:4]([Cl:7])([Cl:5])[C:12]1[CH:13]=[CH:14][C:9]([F:8])=[CH:10][CH:11]=1)[CH3:3]

Participants

3

Reactant 2

HCID 97643Silane, trichloro(1-chloroethyl)-HCID 178418676HCID 178418676, compound

Product 1

HCID 19382023HCID 19382023, compound

Procedure

In the same apparatus and procedures as Example 6 were reacted 10.6 g (0.051 mol) of (α-chloroethyl)trichlorosilane and 26 ml of 4-fluorophenylmagnesiumbromide (2.0 M in diethylether) to give (α-chloroethyl)dichloro(4-fluorophenyl) silane.

Sources & evidence

ORD record
ord-88a94f71a2c949219e27d46fd02c73d6
Source dataset
uspto-grants-1995_10
Patent number
US05455356

Reaction notes

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