HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2210287Generated: November 1, 2026
Acetic Acid → 2-Propenoic acid, 3-(4-methoxyphenyl)-, 2-ethylhexyl ester
https://huagongshe.com/reaction/2210287
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | 2-Ethylhexyl acrylate | HCID 7636 | — |
| Reactant | tert-Octylamine | HCID 61017 | — |
| Reactant | 4-Iodoanisole | HCID 69676 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Product | 2-Propenoic acid, 3-(4-methoxyphenyl)-, 2-ethylhexyl ester | HCID 21630 | 92% |
Reaction Steps
A mixture of 4.68 g (20 mmol) of p-iodoanisole, 4.05 g (22 mmol) of 2-ethylhexyl acrylate, 2.84 g (22 mmol) of 1,1,3,3-tetramethylbutylamine, 1.32 g (22 mmol) of acetic acid and 32 mg of palladium on charcoal (5%) is stirred at 150° C. for 3 hours. After working up as in Example 1 there is obtained 2-ethylhexyl p-methoxycinnamate in 92% yield.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US05457226 |
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| Source dataset | uspto-grants-1995_10 |
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| ORD ID | ord-94d19c1a66ae41b094f1b3d61bb9a886 |
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| Source note | uspto-grants-1995_10 |
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