HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → 2-Propenoic acid, 3-(4-methoxyphenyl)-, 2-ethylhexyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | 4-Iodoanisole | HCID 69676 | — |
| Reactant | 2-Ethylhexyl beta-diethylamino-propionate | HCID 19380269 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Product | 2-Propenoic acid, 3-(4-methoxyphenyl)-, 2-ethylhexyl ester | HCID 21630 | 93% |
Reaction Conditions
| Temperature | 150 °C |
|---|
Reaction Steps
A mixture of 2.34 g (10 mmol) of p-iodoanisole, 2.57 g (10 mmol) of 2-ethylhexyl β-diethylamino-propionate, 0.9 g (15 mmol) of acetic acid and 15 mg of palladium on charcoal (5%) is stirred at 150° C. for 2 hours. Therafter, the mixture is worked up as in Example 1. 2-Ethylhexyl p-methoxycinnamate is obtained in 93% yield.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05457226 |
| Source dataset | uspto-grants-1995_10 |
| ORD ID | ord-17ff5446d4d940539aada0ddc9da3d6a |
| Source note | uspto-grants-1995_10 |