HuagongsheHuagongshe Chemistry Print Report · For research reference only
N,N-Dimethylaniline → HCID 19375799, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | N,N-Dimethylaniline | HCID 949 | — |
| Reactant | Methyl 4-{3-[(prop-2-en-1-yl)oxy]phenoxy}benzoate | HCID 19375796 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | HCID 19375799 | HCID 19375799 | 92% |
Reaction Steps
A solution of methyl 4-(3-allyloxyphenoxy)benzoate in N,N-dimethylaniline was heated at 190° C. for 19 hours, cooled, diluted with ethyl acetate, washed with aqueous hydrochloric acid, dried, and evaporated in vacuo. The residue was chromatographed on silica gel eluting with hexane/ethyl ether to give a 40:60 mixture of the title compounds as an oil in 92% yield. NMR.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05462954 |
| Source dataset | uspto-grants-1995_10 |
| ORD ID | ord-429bfc0a93ec4f019d89a38b1c45c279 |
| Source note | uspto-grants-1995_10 |