Tributylvinyltin → HCID 69587393, compound

Participants

Reaction Conditions

Reaction Steps

In a reactor equipped with a stirrer and a reflux condenser, 2.0 g (0.0059 mol) of m-tolyl(p-bromophenyl)phenylamine, 0.18 g (0.00015 mol) of tetrakistriphenylphosphine palladium (0), 0.005 g of 2,6-dibutylhydroxytoluene and 20 ml of toluene were added and dissolved, and then 2.1 ml (0.0071 mol) of tributyl(vinyl)tin was added to the mixture in an argon gas atmosphere at room temperature. The mixture was heated to 100° C. and continuously stirred for 76 hours. After air cooling, the solvent was distilled off, and the residue was purified by silica gel column chromatography (developing solvent: hexane) to yield 1.4 g of m-tolyl(p-vinylphenyl)phenylamine as a colorless liquid at a yield of 81%.

Provenance & Evidence