HCID 86602634, compound → HCID 86602636, compound

HRID 2212495Notes

Reaction equation

HRID 2212495 reaction equation
[Si:1]([O:8][C@H:9]1[CH2:14][C@@H:13]([OH:15])[CH2:12][CH2:11][C@@H:10]1[NH:16][C:17](=[O:23])[O:18][C:19]([CH3:22])([CH3:21])[CH3:20])([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2].[Si](O[C@@H]1C[C@@H](O)CC[C@H]1NC(=O)OC(C)(C)C)(C(C)(C)C)(C)C>>[Si:1]([O:8][C@H:9]1[CH2:14][C:13](=[O:15])[CH2:12][CH2:11][C@@H:10]1[NH:16][C:17](=[O:23])[O:18][C:19]([CH3:22])([CH3:21])[CH3:20])([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2]

Participants

3

Reactant 2

HCID 86602634HCID 86602634, compound2×HCID 90744006HCID 90744006, compound

Product 1

HCID 86602636HCID 86602636, compound

Procedure

tert-Butyl (1S,2S)-2-(tert-butyldimethylsilyloxy)-4-oxocyclohexylcarbamate was prepared from tert-butyl (1S,2S,4S)-2-(tert-butyldimethylsilyloxy)-4-hydroxycyclohexylcarbamate (41A) as described in 40A. It was converted to the product as described in 40A.

Sources & evidence

ORD record
ord-c7c7c27177534355b0ce9c617352733a
Source dataset
uspto-grants-2006_09
Patent number
US07102003B2

Reaction notes

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