Pyridinium hydrochloride → 307000-42-6

HRID 2213695Notes

Reaction equation

HRID 2213695 reaction equation
[C:1]([C:5]1[CH:19]=[CH:18][C:17]([CH3:20])=[CH:16][C:6]=1[O:7][C:8]1[CH:13]=[CH:12][C:11]([O:14]C)=[CH:10][CH:9]=1)([CH3:4])([CH3:3])[CH3:2].Cl.[NH+]1C=CC=CC=1>O>[C:1]([C:5]1[CH:19]=[CH:18][C:17]([CH3:20])=[CH:16][C:6]=1[O:7][C:8]1[CH:13]=[CH:12][C:11]([OH:14])=[CH:10][CH:9]=1)([CH3:4])([CH3:3])[CH3:2]

Participants

4

Reactant 2

HCID 21584435Pyridinium hydrochlorideHCID 21958107HCID 21958107, compound

Product 1

HCID 9859903307000-42-6

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

7.1 g (0.026 mol) of 4-(2-t-Butyl-5-methylphenoxy)-methoxybenzene are heated with 15.0 g (0.13 mol) pyridinium hydrochloride to 180° C. for 6 h. After cooling water is added and the reaction mass is extracted with xylene. The product is distilled after evaporation of xylene at 130° C./0.01 Torr and recrystallized from petrol ether (80–110 to yield colourless crystals (mp 102° C.).

Workup

  1. additionis added
  2. extractionthe reaction mass is extracted with xylene
  3. distillationThe product is distilled
  4. customafter evaporation of xylene at 130° C./0.01 Torr
  5. customrecrystallized from petrol ether (80–110

Sources & evidence

ORD record
ord-62d2d05af6f94d0882e03113e16937f9
Source dataset
uspto-grants-2006_09
Patent number
US07105577B2

Reaction notes

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