Phenylacetylene → HCID 11470391, compound

HRID 2213967Notes

Reaction equation

HRID 2213967 reaction equation
[CH:1]#[C:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7]C.C1(C#C)C=CC=CC=1.[CH:17]1[C:26]2[C:21](=[CH:22][CH:23]=[CH:24][CH:25]=2)[CH:20]=[CH:19][C:18]=1[C:27]#N>C(#N)C1C=CC=CC=1>[C:27]([C:18]1[CH:19]=[CH:20][C:21]2[C:26](=[CH:25][CH:24]=[CH:23][CH:22]=2)[CH:17]=1)#[C:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7]

Participants

5

Reactant 3

HCID 10821PhenylacetyleneHCID 119442-NaphthalenecarbonitrileHCID 123701-Octyne

Product 1

HCID 11470391HCID 11470391, compoundYield 99%

Reagents, catalysts & solvents 1

HCID 7505BenzonitrileSolvent

Procedure

The procedure was identical to Example 2, with the exception that 1-octyne (0.590 ml; 0.441 g; 4.00 mmol) was used as a substrate instead of phenylacetylene and 2-naphthonitrile (0.306 g; 2.00 mmol) was used as a substrate instead of benzonitrile. GC analysis of the organic phase of the hydrolyzed reaction sample after 22 h at 65° C. showed the presence of 1.98 mmol (99% yield) of 2-(1-octynyl)naphthalene and no remaining 2-naphthonitrile in the reaction mixture.

Sources & evidence

ORD record
ord-44b32b9f9a7c46e9ac8df5380d079e06
Source dataset
uspto-grants-2006_09
Patent number
US07105707B2

Reaction notes

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