Trichlorosilane → HCID 21953394, compound

HRID 2215867Notes

Reaction equation

HRID 2215867 reaction equation
[C:1]1([S:7][CH2:8]Cl)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Cl:10][SiH:11]([Cl:13])[Cl:12]>[Cl-].C([P+](CCCC)(CCCC)CCCC)CCC>[C:1]1([S:7][CH2:8][Si:11]([Cl:13])([Cl:12])[Cl:10])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

4

Reactant 2

HCID 24811TrichlorosilaneHCID 81623Chloromethyl phenyl sulphide

Product 1

HCID 21953394HCID 21953394, compoundYield 44.6%

Reagents, catalysts & solvents 1

HCID 75311Tetrabutylphosphonium chlorideCatalyst

Procedure

As in Example 1, phenylthiomethyl chloride (2.97 g, 0.0187 mol)), trichlorosilane (7.61 g, 0.0562 mol) and tetrabutylphosphonium chloride (2.97 g, 0.0187 mol) were put in a 50 mL stainless steel tube under nitrogen atmosphere. The reaction chamber was closed with a cover and the reaction was carried out at 120° C. for 12 hours. This reaction mixture was distilled under low pressure to give 2.15 g of (phenylthiomethyl)trichlorosilane in 44.5% yield.

Workup

  1. customThe reaction chamber was closed with a cover
  2. distillationThis reaction mixture was distilled under low pressure

Sources & evidence

ORD record
ord-4eb4cda8e474443590d46eff9f773dc9
Source dataset
uspto-grants-2006_09
Patent number
US07109367B1

Reaction notes

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