Ammonium Chloride → HCID 15865176, compound

Participants

Reaction Steps

A solution of 24 g (0.2 mol) of 3,6,6-trimethylfulvene in 100 mL of ether was added at 78° C. under argon atmosphere to a solution of 7.59 g (0.2 mol) of lithium aluminium hydride in 200 mL of ether. The reaction mixture was allowed to warm to room temperature, stirred for 2 h and then treated with a 10% aq. solution of NH4Cl. The organic phase was collected, washed with water, dried with MgSO4 and concentrated. The residue was distilled at 63° C./50 mmHg. Yield 15.88 g (65%).The desired title compound was characterized by 1H-NR

Provenance & Evidence