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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2217123Generated: November 3, 2026

(3S,6S)-Octane-3,6-diol → 2,3-bis[(2R,5R)-2,5-diethyl-phospholan-1-yl)-benzo[b]thiophene

https://huagongshe.com/reaction/2217123

Reaction equation

Participants

RoleNameHCIDCharge
Reactant(3S,6S)-Octane-3,6-diolHCID 7009316—
Reactant2,3-Bisphosphinobenzo[b]thiopheneHCID 11658457—
Product2,3-bis[(2R,5R)-2,5-diethyl-phospholan-1-yl)-benzo[b]thiopheneHCID 8659562048%

Reaction Steps

In analogy to Example 11, the cyclic sulfate derived from (3S,6S)-3,6-octanediol is reacted with 2,3-bisphosphinobenzo[b]thiophene to give the title compound in 48% yield.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS07407910B2
Source datasetuspto-grants-2008_08
ORD IDord-db4f32fd865d40bf83355a9fb1f3503e
Source noteuspto-grants-2008_08