HuagongsheHuagongshe Chemistry Print Report · For research reference only
Iodoethane → tert-Butyl ethyl(prop-2-en-1-yl)carbamate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Iodoethane | HCID 6340 | — |
| Reactant | Sodium hydride | HCID 24758 | — |
| Reactant | tert-butyl N-(prop-2-en-1-yl)carbamate | HCID 4067274 | — |
| Solvent | N-methyl-2-pyrrolidone | HCID 13387 | — |
| Product | tert-Butyl ethyl(prop-2-en-1-yl)carbamate | HCID 71365398 | — |
Reaction Steps
Sodium hydride (60%, 0.25 g) was added to tert-butyl allylcarbamate (1.0 g) in anhydrous N-methylpyrrolidinone (4 ml) followed by ethyl iodide (1.6 ml). The crude product was purified by chromatography (SiO2, isohexane:ethyl acetate 19:1 as eluant) to afford the sub-title compound (0.53 g) as a colourless oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07408065B2 |
| Source dataset | uspto-grants-2008_08 |
| ORD ID | ord-fb37e5e960534434a49a43f6252648c9 |
| Source note | uspto-grants-2008_08 |